Fresh and Hardened Properties of High Calcium Fly Ash-Based Geopolymer Matrix with High Dosage of Borax

Antoni, and PURWANTORO, AUSTIN ADIPUTRA TAHIR and SUYANTO, WIDYA SARI PUSPA DEWI and Hardjito, Djwantoro (2019) Fresh and Hardened Properties of High Calcium Fly Ash-Based Geopolymer Matrix with High Dosage of Borax. [UNSPECIFIED]

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Abstract

Geopolymer is synthesized by mixing material rich in alumina and silica, such as fly ash, with a highly alkaline solution to form a hardened matrix. However, when using high calcium fly ash as a precursor, a flash set frequently occurs, i.e., the mixture hardens very rapidly before casting can be completed. The use of borax as an additive has been reported due to its potential to prolong the setting time. In this study, the use of a significantly higher dosage of borax is explored. The results show that the addition of borax up to 20% of fly ash, by mass, into the alkaline solution prolongs the setting time by up to 90 min. Conversely, the addition of higher amounts of borax tends to decrease the compressive strength of the geopolymer, whereas adding a small amount of calcium oxide into the mixture increases the strength marginally, especially when the borax content is small. However, the amount of calcium oxide should be limited because at higher content, the effectiveness of borax to prolong the setting time is reduced.

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